This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2025.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | Abbotsleigh | Wahroonga | German Extension | Gong, Shuochen Caitlin |
| 2 | Abbotsleigh | Wahroonga | German Extension | Lung, Cecilia Hei-Yee |
| 3 | Ascham School | Edgecliff | German Extension | Finkelstein, Ava |
| 4 | Covenant Christian School | Belrose | German Extension | Soldani, Isabel Mary |
| 5 | Fort Street High School | Petersham | German Extension | Howes, Emma |
| 6 | Fort Street High School | Petersham | German Extension | Hurley-Stone, Emil |
| 7 | Fort Street High School | Petersham | German Extension | McIntyre, Lachlan |
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| 8 | Fort Street High School | Petersham | German Extension | Robertson, Archie |
| 9 | International Grammar School | Ultimo | German Extension | Decker-Stewart, Bruno |
| 10 | International Grammar School | Ultimo | German Extension | Gaertner, Greta |
| 11 | International Grammar School | Ultimo | German Extension | Hadassin, Benjamin |
| 12 | International Grammar School | Ultimo | German Extension | Linzer, Anne-Catherine |
| 13 | International Grammar School | Ultimo | German Extension | Randall, Matilda |
| 14 | Knox Grammar School | Wahroonga | German Extension | Gooden, Nicholas Walter |
| 15 | Kogarah High School | Kogarah | German Extension | Flachskampf, Amelie |
| 16 | Kotara High School | Adamstown | German Extension | Doherty, Samuel James |
| 17 | Mosman High School | Mosman | German Extension | Schief, Nina |
| 18 | North Sydney Boys High School | Crows Nest | German Extension | Huo, Cody |
| 19 | North Sydney Boys High School | Crows Nest | German Extension | Liu, Justin |
| 20 | North Sydney Boys High School | Crows Nest | German Extension | Pi, Anthony |
| 21 | North Sydney Boys High School | Crows Nest | German Extension | Shah, Param |
| 22 | North Sydney Boys High School | Crows Nest | German Extension | Wei, Lawrence |
| 23 | North Sydney Girls High School | Crows Nest | German Extension | Lynch, Agnetha |
| 24 | Northern Beaches Secondary College Manly Campus | North Curl Curl | German Extension | Taylor, Mia-Francesca Tesoriero |
| 25 | Presbyterian Ladies College Sydney | Croydon | German Extension | Ratnavadivel, Alessa |
| 26 | Ravenswood School for Girls | Gordon | German Extension | Neame, Gemma |
| 27 | Roseville College | Roseville | German Extension | Gruettke, Saskia |
| 28 | SHORE Sydney Church of England Grammar School | North Sydney | German Extension | Higgs, Daniel Werner |
| 29 | SHORE Sydney Church of England Grammar School | North Sydney | German Extension | Spark, Ethan David Adrian |
| 30 | St Andrews Cathedral School | Sydney | German Extension | Clark, Abigail |
| 31 | St Clares Catholic High School | Hassall Grove | German Extension | Trad, Abdulla |
| 32 | St Lukes Grammar School | Dee Why | German Extension | Dicke, Sophia |
| 33 | Sydney Girls High School | Surry Hills | German Extension | Moritz, Rebekka Mackinnon |
| 34 | Sydney Grammar School | Darlinghurst | German Extension | Eibl, Felix |
| 35 | The Kings School | North Parramatta | German Extension | Ball, Sebastian |
| 36 | The Kings School | North Parramatta | German Extension | Sampson, Johannes |