This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2020.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | Ascham School | Edgecliff | German Extension | Brand, Alexandra |
| 2 | Ascham School | Edgecliff | German Extension | Deva, Anika |
| 3 | Erina High School | Erina | German Extension | Sesko, Laura |
| 4 | Fort Street High School | Petersham | German Extension | Faith, Julius Hiroshi |
| 5 | Fort Street High School | Petersham | German Extension | Gard, Bridget Holly |
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| 6 | Fort Street High School | Petersham | German Extension | Grimes, Emily Elisabeth |
| 7 | Glenaeon Rudolf Steiner School | Middle Cove | German Extension | Candotti, Chiara |
| 8 | Glenaeon Rudolf Steiner School | Middle Cove | German Extension | Hall-Whitington, Nelson |
| 9 | Knox Grammar School | Wahroonga | German Extension | Browne, Nicholas Alexander |
| 10 | Knox Grammar School | Wahroonga | German Extension | Buddee, Mark Frederick |
| 11 | Knox Grammar School | Wahroonga | German Extension | Mountstephens, Thomas Richard |
| 12 | North Sydney Boys High School | Crows Nest | German Extension | Alvarez Rodriguez, Luis |
| 13 | North Sydney Boys High School | Crows Nest | German Extension | Go, Vincent |
| 14 | North Sydney Boys High School | Crows Nest | German Extension | Jiang, Daniel |
| 15 | North Sydney Boys High School | Crows Nest | German Extension | Leung, Donren |
| 16 | North Sydney Boys High School | Crows Nest | German Extension | Shi, Edmond |
| 17 | North Sydney Boys High School | Crows Nest | German Extension | Silcock, Rowan |
| 18 | North Sydney Boys High School | Crows Nest | German Extension | Sunwoo, Jin |
| 19 | Ravenswood School for Girls | Gordon | German Extension | Cowdery, Jacqueline |
| 20 | SCEGGS Darlinghurst | Darlinghurst | German Extension | Robson, Elizabeth |
| 21 | SHORE Sydney Church of England Grammar School | North Sydney | German Extension | McCook, Oskar Arthur |
| 22 | Sydney Grammar School | Darlinghurst | German Extension | Latham, Connor |
| 23 | Sydney Grammar School | Darlinghurst | German Extension | Lawson, Jonathan |
| 24 | Sydney Grammar School | Darlinghurst | German Extension | Seifried, Oscar |
| 25 | The Kings School | North Parramatta | German Extension | Cooke, Mackenzie Shanley Bowden |
| 26 | The Kings School | North Parramatta | German Extension | Owen, Lachlan James |
| 27 | The Kings School | North Parramatta | German Extension | Poolman, George William |
| 28 | The Kings School | North Parramatta | German Extension | Shor, Marcus |
| 29 | The Kings School | North Parramatta | German Extension | Walsh, Nicholas James Woollcombe |