This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2014.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | Brigidine College St Ives | St Ives | Spanish Beginners | Ball, Natalie |
| 2 | Fairvale High School | Fairfield West | Spanish Beginners | Jager, Karina |
| 3 | Great Lakes College Tuncurry Senior Campus | Tuncurry | Spanish Beginners | Gilfillan, Katie |
| 4 | Hornsby Girls High School | Hornsby | Spanish Beginners | Crane, Hannah |
| 5 | Hornsby Girls High School | Hornsby | Spanish Beginners | Dewendra, Sulithi |
| 6 | Hornsby Girls High School | Hornsby | Spanish Beginners | Luca, Simone |
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| 7 | Hornsby Girls High School | Hornsby | Spanish Beginners | Malaney, Michelle |
| 8 | Hornsby Girls High School | Hornsby | Spanish Beginners | Wu, Xiaoyin |
| 9 | Ku-ring-gai High School | North Turramurra | Spanish Beginners | Koolen, Jasper |
| 10 | Ku-ring-gai High School | North Turramurra | Spanish Beginners | Taylor, Sean Phillip |
| 11 | Ku-ring-gai High School | North Turramurra | Spanish Beginners | White, Lachlan Anthony |
| 12 | MLC School | Burwood | Spanish Beginners | Aravena, Milena |
| 13 | Moriah College | Queens Park | Spanish Beginners | Fleischer, Daniel |
| 14 | Moriah College | Queens Park | Spanish Beginners | Shein, Daniel |
| 15 | Moriah College | Queens Park | Spanish Beginners | Vidor, Talia |
| 16 | Mosman High School | Mosman | Spanish Beginners | Anderiesen, Mitchell Crawford |
| 17 | Newington College | Stanmore | Spanish Beginners | Macarounas, David Thomas |
| 18 | Newington College | Stanmore | Spanish Beginners | Minguez, Damien |
| 19 | Randwick Girls High School | Randwick | Spanish Beginners | Mobbs, Samara Drayton |
| 20 | Richard Johnson Anglican College | Oakhurst | Spanish Beginners | Blanco, Hannah |
| 21 | St Catherines School | Waverley | Spanish Beginners | Ballesteros, Sofia |
| 22 | St Catherines School | Waverley | Spanish Beginners | Bartlett, Madison |
| 23 | St Catherines School | Waverley | Spanish Beginners | Chia, Jacquelyn |
| 24 | St Catherines School | Waverley | Spanish Beginners | Mills, Gabrielle |
| 25 | St Ives High School | St Ives | Spanish Beginners | Kartashova, Dar'ya |
| 26 | St Ives High School | St Ives | Spanish Beginners | Manton-Hall, Georgia Elizabeth |
| 27 | St Ives High School | St Ives | Spanish Beginners | Tome, Zacary Dalai |
| 28 | St Marys Senior High School | St Marys | Spanish Beginners | Waddell, Chelsea May |
| 29 | St Scholasticas College Glebe Point | Glebe Point | Spanish Beginners | Rowell, Stephanie |
| 30 | Wycliffe Christian School | Warrimoo | Spanish Beginners | Dove, Christopher |