This report lists the school, subject and student names of every HSC band 6 or band E4 result that was awarded in 2012.
Note that where a student has undertaken studies at more than one school, the student's main school is shown.
| 1 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Extension | Ahtypis, Jana |
| 2 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Extension | Kontakos, Martina |
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| 3 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Extension | Proestos, Theophanis |
| 4 | All Saints Greek Orthodox Grammar School | Belmore | Modern Greek Extension | Skylitsis, Dimitrios |
| 5 | Blakehurst High School | Blakehurst | Modern Greek Extension | Danas, Nicholetta |
| 6 | Casimir Catholic College | Marrickville | Modern Greek Extension | Kouzinos, Sophia |
| 7 | Galstaun College | Ingleside | Modern Greek Extension | Manoukian, Krikor |
| 8 | Georges River College Oatley Senior Campus | Oatley | Modern Greek Extension | Koutroumpas, Konstantinos |
| 9 | Jamison High School | South Penrith | Modern Greek Extension | Fassoulidis, Kleanthi |
| 10 | Loyola Senior High School | Mount Druitt | Modern Greek Extension | Issa, Rita |
| 11 | St Euphemia College | Bankstown | Modern Greek Extension | Souris, Angelique |
| 12 | St Spyridon College Senior School | Maroubra | Modern Greek Extension | Anagnostakis, Vicky |
| 13 | St Spyridon College Senior School | Maroubra | Modern Greek Extension | Nicholson, Andreas |
| 14 | Trinity Grammar School | Summer Hill | Modern Greek Extension | Sidiropoulos, Dimitri Elias |