| 1866 | Pymble Ladies College | Pymble | Latin Extension | 5 |
| 1867 | Queenwood School for Girls | Mosman | Biology | 5 |
| 1868 | Queenwood School for Girls | Mosman | Design and Technology | 5 |
| 1869 | Queenwood School for Girls | Mosman | Drama | 5 |
| 1870 | Queenwood School for Girls | Mosman | Economics | 5 |
| 1871 | Randwick Boys High School | Randwick | Music 1 | 5 |
| 1872 | Randwick Girls High School | Randwick | Visual Arts | 5 |
| 1873 | Ravenswood School for Girls | Gordon | Food Technology | 5 |
| 1874 | Red Bend Catholic College | Forbes | Personal Development, Health and Physical Education | 5 |
| 1875 | Reddam House Bondi Campus | North Bondi | Ancient History | 5 |
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| 1876 | Reddam House Bondi Campus | North Bondi | Music Extension | 5 |
| 1877 | Reddam House Bondi Campus | North Bondi | Software Design and Development | 5 |
| 1878 | Riverside Girls High School | Gladesville | Business Studies | 5 |
| 1879 | Riverside Girls High School | Gladesville | Mathematics Standard 2 | 5 |
| 1880 | Riverside Girls High School | Gladesville | Visual Arts | 5 |
| 1881 | Rose Bay Secondary College | Dover Heights | Mathematics Extension 1 | 5 |
| 1882 | Rosebank College | Five Dock | Chinese Continuers | 5 |
| 1883 | Rosebank College | Five Dock | Hospitality Examination | 5 |
| 1884 | Roseville College | Roseville | History Extension | 5 |
| 1885 | Roseville College | Roseville | Modern History | 5 |
| 1886 | Ryde Secondary College | Ryde | Indonesian Continuers | 5 |
| 1887 | Ryde Secondary College | Ryde | Visual Arts | 5 |
| 1888 | SCEGGS Darlinghurst | Darlinghurst | History Extension | 5 |
| 1889 | SCEGGS Darlinghurst | Darlinghurst | Mathematics Extension 2 | 5 |
| 1890 | Sefton High School | Sefton | English Extension 1 | 5 |
| 1891 | Sefton High School | Sefton | Legal Studies | 5 |
| 1892 | Sefton High School | Sefton | Physics | 5 |
| 1893 | SHORE Sydney Church of England Grammar School | North Sydney | Biology | 5 |
| 1894 | SHORE Sydney Church of England Grammar School | North Sydney | Music 1 | 5 |
| 1895 | SHORE Sydney Church of England Grammar School | North Sydney | Studies of Religion I | 5 |
| 1896 | Smiths Hill High School | Wollongong | Visual Arts | 5 |
| 1897 | Snowy Mountains Grammar School | Jindabyne | English Advanced | 5 |
| 1898 | Springwood High School | Springwood | Textiles and Design | 5 |
| 1899 | St Aloysius College | Milsons Point | Music 2 | 5 |
| 1900 | St Andrews Cathedral School | Sydney | Music 1 | 5 |
| 1901 | St Andrews College Senior Campus | Marayong | History Extension | 5 |
| 1902 | St Augustines College | Brookvale | Drama | 5 |
| 1903 | St Augustines College | Brookvale | Engineering Studies | 5 |
| 1904 | St Catherines School | Waverley | Biology | 5 |
| 1905 | St Catherines School | Waverley | Economics | 5 |
| 1906 | St Catherines School | Waverley | Geography | 5 |
| 1907 | St Catherines School | Waverley | Music 2 | 5 |
| 1908 | St Catherines School | Waverley | Personal Development, Health and Physical Education | 5 |
| 1909 | St Catherines School | Waverley | Studies of Religion I | 5 |
| 1910 | St Catherines School | Waverley | Visual Arts | 5 |
| 1911 | St Charbels College | Punchbowl | English Advanced | 5 |
| 1912 | St Charbels College | Punchbowl | Mathematics Standard 2 | 5 |
| 1913 | St Clares College | Waverley | Mathematics Advanced | 5 |
| 1914 | St Clares High School | Taree | Drama | 5 |
| 1915 | St Columba Anglican School | Port Macquarie | Drama | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 6 Sep 2023