| 1976 | St Francis De Sales Regional College | Leeton | Mathematics General 2 | 5 |
| 1977 | St Francis Xaviers College | Hamilton | Biology | 5 |
| 1978 | St Francis Xaviers College | Hamilton | Mathematics Extension 1 | 5 |
| 1979 | St George Girls High School | Kogarah | Information Processes and Technology | 5 |
| 1980 | St George Girls High School | Kogarah | Personal Development, Health and Physical Education | 5 |
| 1981 | St Ignatius College | Lane Cove | Latin Extension | 5 |
| 1982 | St Ignatius College | Lane Cove | Mathematics Extension 2 | 5 |
| 1983 | St John Bosco College | Engadine | Design and Technology | 5 |
| 1984 | St John Bosco College | Engadine | Geography | 5 |
| 1985 | St John Paul College | Coffs Harbour | Senior Science | 5 |
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| 1986 | St John Paul College | Coffs Harbour | Visual Arts | 5 |
| 1987 | St John Paul II Catholic College Nirimba | Nirimba Fields | Music 1 | 5 |
| 1988 | St John The Evangelist Catholic High School | Nowra | Studies of Religion I | 5 |
| 1989 | St Josephs Catholic High School | Albion Park | English (Advanced) | 5 |
| 1990 | St Josephs Catholic High School | Albion Park | Mathematics | 5 |
| 1991 | St Josephs College Hunters Hill | Hunters Hill | Economics | 5 |
| 1992 | St Josephs College Hunters Hill | Hunters Hill | English Extension 1 | 5 |
| 1993 | St Josephs College Hunters Hill | Hunters Hill | Music 1 | 5 |
| 1994 | St Josephs Regional College | Port Macquarie | English (Advanced) | 5 |
| 1995 | St Josephs Regional College | Port Macquarie | Food Technology | 5 |
| 1996 | St Leos Catholic College | Wahroonga | Studies of Religion II | 5 |
| 1997 | St Lukes Grammar School | Dee Why | Design and Technology | 5 |
| 1998 | St Lukes Grammar School | Dee Why | Studies of Religion I | 5 |
| 1999 | St Marys Senior High School | St Marys | Visual Arts | 5 |
| 2000 | St Patricks College Campbelltown | Campbelltown | Community and Family Studies | 5 |
| 2001 | St Patricks College Strathfield | Strathfield | English Extension 1 | 5 |
| 2002 | St Patricks College Strathfield | Strathfield | Legal Studies | 5 |
| 2003 | St Patricks College Sutherland | Sutherland | English Extension 1 | 5 |
| 2004 | St Patricks College Sutherland | Sutherland | Legal Studies | 5 |
| 2005 | St Patricks Marist College | Dundas | Business Studies | 5 |
| 2006 | St Patricks Marist College | Dundas | Senior Science | 5 |
| 2007 | St Pauls Catholic College Greystanes | Greystanes | Mathematics Extension 1 | 5 |
| 2008 | St Peters Catholic College | Tuggerah | Music 1 | 5 |
| 2009 | St Pius X College | Chatswood | Chemistry | 5 |
| 2010 | St Pius X College | Chatswood | English Extension 1 | 5 |
| 2011 | St Pius X College | Chatswood | Mathematics General 2 | 5 |
| 2012 | St Spyridon College Senior School | Maroubra | Modern Greek Continuers | 5 |
| 2013 | St Ursulas College | Kingsgrove | English (Standard) | 5 |
| 2014 | St Vincents College | Potts Point | Drama | 5 |
| 2015 | St Vincents College | Potts Point | Mathematics General 2 | 5 |
| 2016 | St Vincents College | Potts Point | Personal Development, Health and Physical Education | 5 |
| 2017 | Stella Maris College | Manly | Biology | 5 |
| 2018 | Stella Maris College | Manly | Studies of Religion I | 5 |
| 2019 | Strathfield Girls High School | Strathfield | Business Studies | 5 |
| 2020 | Strathfield Girls High School | Strathfield | Food Technology | 5 |
| 2021 | Strathfield Girls High School | Strathfield | Mathematics General 2 | 5 |
| 2022 | Sydney Girls High School | Surry Hills | Heritage Chinese (Mandarin) | 5 |
| 2023 | Sydney Girls High School | Surry Hills | Visual Arts | 5 |
| 2024 | Sydney Grammar School | Darlinghurst | English Extension 2 | 5 |
| 2025 | Sydney Secondary College Blackwattle Bay Campus | Glebe | Modern History | 5 |
Source: NSW Education Standards Authority (NESA).
Supplementary data from school publications.
Supplementary data from school publications.
Last Updated: 24 Oct 2024